3.
Corrosion
inhibition of zinc in sodium tartrate solution and some
environmental water samples using 3-amino, 4, 6- dimethyle,
thieno[2,3-b] pyridine -2-carboxylic acid and insulating poly(vinyl
pyrrolidine matrix
Seddique M. Ahmed*, Ali A. Mutair, Ahmed S AL-Kamaly, and
Mahmoud A. AL-Amery
Chemistry Department, Faculty of Applied Science, Taiz
University, Taiz – Yemen
Correspondence to: e. mail:
sm-ahmed@yahoo.com
Abstract:
The corrosion inhibition of zinc in tartrate solution in the
absence and in the presence of
3-Amino-4,6-dimethyle,thieno[2,3-b] pyridine-2-Carboxylic
acid (ADTP) and/or insulating Poly(vinyl Pyrrolidine(PVP)
matrix was investigated. The corrosion inhibitive action of
these compounds on zinc metal was studied using
electrochemical (Open Circuit and Galvanostatic polarization
techniques). The thermodynamic parameters for corrosion of
zinc were determined. The effect of natural water samples
in Taiz-city (Yemen) such as Red Sea water, under-ground
water, Tab-water and bottled-water on corrosion rate of zinc
have been studied. It was noticed that the thermodynamic
parameters from derived polarization technique measurements
that ∆Had for the adsorption of and resulted in a positive
value (endothermic). The adsorption typed is a
physical-chemical adsorption. The heats of adsorption and
free energies of adsorption are negative; this suggests that
there is a strong interaction of the inhibitor molecules
with the metal surface resulting in their spontaneous
adsorption forming a highly adherent film [1].
Keywords:
Corrosion, Zinc, Tartrate, Water
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