10.
Effect of Natural Polymeric Substance on Corrosion Rate of AA7075
Aluminum Alloy in Caustic Soda Solution
Auwal,
K. & Mohammed,S.M.
Department of Metallurgical &
Materials Engineering, Ahmadu Bello university, Zaria-Nigeria
E-mail:
akasim2005@yahoo.com
,
salehshuaibmohammed@yahoo.com
Abstract:
The corrosion inhibition of polymeric substance(agar-agar ) on
sand cast AA7075 aluminium alloy in 0.5M solution of NaOH was
studied using weight loss method. The alloy of composition 5.6%Zn,
2.5%Mg, 1.6%Cu, 0.23%Cr and the balance Al was sand cast. After
casting, the alloy was cut and machined to corrosion coupons and
immersed into 0.5M solution of NaOH containing the inhibitor
solution at temperatures of 25, 35, 45, 55 and 65˚C respectively.
Results obtained revealed that agar-agar inhibited/retarded the
corrosion rate of AA7075 in the concentration and temperature
ranges studied. The maximum inhibition efficiency (%IE) of
78.89% was achieved at 25˚C, while the minimum inhibition
efficiency (%IE) of 12.71% was obtained at 65˚C. It was evident
from the result generated that the inhibition efficiency
decreases with increase in experimental temperature. The
activation energy of the inhibited system (Eai =
2460KJ/mol) is greater than for the uninhibited system (Eau
=1660KJ/mol) which further confirms that the presence of agar-agar
retards the corrosion rates of AA7075 in 0.5M NaOH solution.
KEYWORDS: Corrosion, inhibitors, adsorption, inhibition
efficiency.
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